Synthesis and Application of [2.2]Paracyclophane Derivatives in Catalysis and Material Science
Logos
ISBN 978-3-8325-5412-5
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Bibliografische Daten
Fachbuch
Buch. Softcover
2021
In englischer Sprache
Umfang: 215 S.
Format (B x L): 14,5 x 21 cm
Verlag: Logos
ISBN: 978-3-8325-5412-5
Weiterführende bibliografische Daten
Das Werk ist Teil der Reihe: Beiträge zur organischen Synthese; 96
Produktbeschreibung
A new method for enantio-separation based on kinetic resolution was developed, which allows the access to enantiomerically pure [2.2]paracyclophane-based building blocks. In a liquid crystal templated chemical vapor deposition process, [2.2]paracyclophanyl alcohols containing an additional central chiral element were evaluated for the self-assembly of nanofibers. Furthermore, the cyclopropanation of a-alkyl-a-diazo compounds with a [2.2]paracyclophane-based rhodium tetracarboxylate complex was investigated. Finally, the rigidity, regioselective functionalization, and transannular communication of [2.2]paracyclophane were exploited in the design of heterobimetallic Au(I)/Ru(II) complexes for the study of metal-to-metal interactions.
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