Synthesis of New [2.2]Paracyclophane Derivatives for Application in Material Sciences
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ISBN 978-3-8325-4997-8
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Bibliografische Daten
Fachbuch
Buch. Softcover
2019
In englischer Sprache
Umfang: 266 S.
Format (B x L): 14,5 x 21 cm
Verlag: Logos
ISBN: 978-3-8325-4997-8
Weiterführende bibliografische Daten
Das Werk ist Teil der Reihe: Beiträge zur organischen Synthese; 82
Produktbeschreibung
This work focuses on establishing synthetic accesses to [2.2]paracyclophane-based derivatives for different applications in materials sciences and supramolecular chemistry in order to exploit transannular communication, steric demand and chirality. In this regard, the first [2.2]paracyclophane-based thermally activated delayed fluorescence (TADF) emitters were developed, chiral chemical vapor deposition (CVD) monomers were synthesized and a new supramolecular guest was synthetically established. During these synthetic endeavors, chemical peculiarities of the [2.2]paracyclophane were observed and investigated, leading to the discovery of para-selective C–H activation and a synthetic access to the novel (1,7)carbazolophane.
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