Brezina

Supramolecular Complexes of Oxoporphyrinogens with Organic Molecules

Springer

ISBN 978-3-031-68645-0

Standardpreis


160,49 €

lieferbar ca. 10 Tage als Sonderdruck ohne Rückgaberecht

Preisangaben inkl. MwSt. Abhängig von der Lieferadresse kann die MwSt. an der Kasse variieren. Weitere Informationen

auch verfügbar als eBook (PDF) für 149,79 €

Bibliografische Daten

Fachbuch

Buch. Hardcover

2025

24 s/w-Abbildungen, 102 Farbabbildungen.

In englischer Sprache

Umfang: xv, 214 S.

Format (B x L): 15,5 x 23,5 cm

Verlag: Springer

ISBN: 978-3-031-68645-0

Produktbeschreibung

Macrocyclic oxoporphyrinogen molecules combine the ability to form strong supramolecular complexes with organic compounds and the ability to absorb light. These properties allow high-sensitivity colorimetric detection of acids in solution in the presence of oxoporphyrinogen. Moreover, protonated oxoporphyrinogens show various molecular dynamic processes on the millisecond timescale. This book offers deep analyses of colorimetric, binding and kinetic properties of oxoporphyrinogen-acid complexes. A detailed introduction is given for: theory of supramolecular binding and chemical kinetics; NMR spectroscopy with emphasis on multi-state chemical exchange including derivation of analytical spectral lineshapes; UV/vis spectroscopy and analysis of UV/vis spectra, using singular value decomposition (SVD). Implementation of the derived models in Mathematica is also provided. The experimental part addresses SVD analysis of UV/vis spectra illuminating the effect of protonation on various oxoporphyrinogen derivatives and explaining the colorimetric response. Furthermore, analysis of chemical exchange lineshapes offers insight into the dynamic processes present in protonated oxoporphyrinogens. The various models and techniques described in this book are widely applicable for other systems.

Autorinnen und Autoren

Kundeninformationen

Provides deep analysis of a unique molecular system from several different perspectives Thoroughly describes multi-state chemical exchange in NMR and application of SVD analysis on UV/vis spectra Offers variety of binding and kinetic models including derivation and implementation in Mathematica

Produktsicherheit

Hersteller

Springer Nature Customer Service Center GmbH

ProductSafety@springernature.com

Topseller & Empfehlungen für Sie

Ihre zuletzt angesehenen Produkte

Rezensionen

Dieses Set enthält folgende Produkte:
    Auch in folgendem Set erhältlich:

    • nach oben

      Ihre Daten werden geladen ...