Erschienen: 20.06.2019 Abbildung von Xiao | Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes | 2019

Xiao

Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

2019. Buch. 125 S. Softcover

Cuvillier Verlag. ISBN 978-3-7369-7034-2

Format (B x L): 14.4 x 21.1 cm

Gewicht: 190 g

In englischer Sprache

Produktbeschreibung

The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).

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